Occupational Exposure to Methylene Chloride (Dichloromethane) CAS# 75014

29CFR 1910.1052 Summary of Requirements

Permissible Exposure Limit (PEL) = 25 part per million (ppm) 8-hour Time-weighted Average (TWA); 125 ppm for a 15-minute TWA (STEL)

Action Level = 12.5 ppm 8-hour TWA

Requirement

> TWA or STEL

³ Action Level

but < TWA

< Action Level

Initial Monitoring

Where present

Where present1

Where present1

Periodic Monitoring2

Quarterly

Every 6 months

No

Employee Notification of Monitoring Results

Within 15 working days3

Within 15 working days

Within 15 working days

Employee Observation of Monitoring

Yes

Yes

Yes

Regulated Work Areas

Yes

No

No

Respiratory Protection

Yes

No

No

Respiratory Protection Program

Yes

No4

No4

Feasible Engineering and work practice controls

Yes

No

No

Job Rotation

Not Allowed

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Leak and Spill Detection and Repair

Yes

Yes

Yes

Skin or Eye Protective clothing5

Yes

Yes

Yes

Hygiene Facilities6

Yes

Yes

Yes

Medical Surveillance7

Yes

Yes

Not required

Hazard Communication on labels and MSDSs

Yes

Yes

Yes

Employee Information and Training

Yes

Yes

Yes

Records Retention- Objective Data

Not Applicable

Not Applicable

Yes8

Records Retention- Exposure Monitoring

30 years

30 years

30 years

Records Retention-

Medical Surveillance

Employment

+ 30 years

Employment

+ 30 years

Not Applicable

Transfer of Records

Consistent with 1910.1020 (h)

Consistent with 1910.1020 (h)

Consistent with 1910.1020 (h)

 

  1. Documentation of objective data indicating that MC can not be released in air concentrations Action Level or > STEL can be used instead of initial monitoring. Also, representative data obtained between April 10, 1996 and April 10, 1997 can be used for the initial monitoring data as long as conditions are similar. If exposures are less than 30 days per year and direct reading data is sufficient to determine appropriate controls, initial monitoring is not needed.
  2. The frequency of periodic monitoring can be decreased when two consecutive measurements, taken at least seven days apart, indicate exposures less than or equal to the PEL. Periodic monitoring can be discontinued when two consecutive measurements, taken at least seven days apart, indicate exposures less than the Action Level or less than or equal to the STEL. Additional monitoring should be conducted when there is a change in workplace conditions that indicates employee exposures may have increased. Examples include changes in products, processes, control equipment, work practices, leaks, ruptures or break downs.
  3. If monitoring results are greater than the PEL-TWA or STEL, the written notification must describe the corrective action planned and schedule for completion of action.
  4. For required or voluntary use of tight fitting respirators, a Respiratory Protection Program is required that as a minimum, meets requirements of 1910.134. If voluntary use is allowed for disposable dust masks selected for nuisance levels of organic vapors, information should be provided to those employees from Appendix D of 1910.134.
  5. Protective equipment should be provided free of charge where there is potential for skin or eye contact with MC. The PPE should be cleaned, laundered or repaired as needed to maintain the effectiveness of the protection. Employers are responsible for disposal of contaminated PPE.
  6. For reasonably foreseeable skin contact with solutions with 0.1% MC, readily available wash facilities should be provided to rinse MC from skin or eyes.
  7. There are a number of specific Medical Surveillance provisions in 1910.1052 (j) including provisions for Medical Removal Protection. You should consult that section of the standard for applicable medical provisions as well as your company physician. Although baseline medical evaluations are not required, it may be prudent to obtain baseline information for employees who may potentially be exposed to MC, even at concentrations below the Action Level.
  8. Objective data should be retained as long as there is reliance on that data.
The information contained in this document is believed to be accurate and has been provided for assistance with requirements for the OSHA Methylene Chloride standard. You should contact your local OSHA office for interpretations of this or any OSHA standard.